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Aquatic Redox Chemistry
Edited by Paul Tratnyek, Timothy Grundl, and Stefan Haderlein
632 pages
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227x152mm
978-0-8412-2652-4
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Hardback
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14 June 2012
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- Provides a comprehensive overview of aquatic redox chemistry through chapters contributed by many of the leading investigators in the field
Oxidation-reduction (redox) reactions are among the most important and interesting chemical reactions that occur in aquatic environmental systems, which include soils, sediments, aquifers, rivers, lakes, estuaries, water treatment and distribution systems, etc. This volume provides a comprehensive overview of aquatic redox chemistry through chapters contributed by many of the leading investigators in the field. Each chapter summarizes core concepts and reports important new developments in areas of priority or
emerging interest, such as the prediction of redox reaction rates and mechanisms, role of redox shuttles in biogeochemistry, interfacial properties of redox active minerals, role of reactive oxygen species in sunlit surface waters, water treatment technologies based on oxidation or reduction, and coupling of redox with transport processes. Fundamental and advanced aspects of each topic are balanced such that the volume can serve as teaching material for upper level students in environmental science or engineering, as well as being a valuable resource for experienced scientists and practitioners.Readership: Researchers and practitioners in environmental services industries who have a graduate-level understanding of
environmenal chemistry
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Edited by Paul Tratnyek, Professor, Division of Environmental and Biomolecular Systems (EBS), Institute of Environmental Health, Oregon Health & Science University, Portland OR, USA, Timothy Grundl, Professor, Geosciences Department and Chair in the School of Freshwater, University of Wisconsin-Milwaukee, Milwaukee, WI, USA, and Stefan Haderlein, Professor, Center for Applied Geosciences (ZAG), Eberhard-Karls University Tübingen, Germany Dr. Paul G. Tratnyek is currently Professor, and Associate Head, in the Division of Environmental and Biomolecular Systems (EBS), Institute of Environmental Health (formerly Oregon Graduate Institute, OGI), at the Oregon Health &
Science University, Portland OR, USA. His research concerns oxidation-reduction reactions and other physico-chemical processes that control the fate and effects of environmental substances, including minerals, metals, organics, and nanoparticles.
Dr. Timothy J. Grundl is currently Professor in the Geosciences Department and Chair in the School of Freshwater Sciences (formerly the Great Lakes WATER Institute) at the University of Wisconsin-Milwaukee, Milwaukee, WI, USA. His research uses environmental tracers in the study of oxidation-reduction reactions, groundwater provenance and recharge dynamics and fate of pollutants in aquifer systems.
Dr. Stefan B. Haderlein is a full Professor at the Center for Applied Geosciences (ZAG) of the Eberhard-Karls University
Tübingen, Germany. His research concerns sorption processes, oxidation-reduction reactions and other physico-chemical processes that control the fate of contaminants in the subsurface as well as stable isotope techniques to trace their origin and fate.
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Preface
1. Introduction to Aquatic Redox Chemistry
Timothy J. Grundl, Stefan Haderlein, James T. Nurmi, and Paul G. Tratnyek
2. Thermodynamic Redox Calculations for One and Two Electron Transfer Steps: Implications for Halide Oxidation and Halogen Environmental Cycling
George W. Luther, III
3. One-Electron Reduction Potentials from Chemical Structure Theory Calculations
Eric J. Bylaska, Alexandra J. Salter-Blanc, and Paul G. Tratnyek
4. Thermodynamic Control on Terminal Electron Transfer and Methanogenesis
Christian Blodau
5. Redox Chemistry and Natural Organic Matter (NOM): Geochemists' Dream, Analytical Chemists>' Nightmare
Donald L. Macalady and Katherine Walton-Day
6. Electron Shuttling by Natural Organic Matter: Twenty Years After
Garrison Sposito
7. Electrochemistry of Natural Organic Matter
James T. Nurmi and Paul G. Tratnyek
8. Pathways Contributing to the Formation and Decay of Ferrous Iron in Sunlit Natural Waters
Shikha Garg, Andrew L. Rose, and T. David Waite
9. The Role of Iron Coordination in the Production of Reactive Oxidants from Ferrous Iron Oxidation by Oxygen and Hydrogen Peroxide
Christina Keenan Remucal and David L. Sedlak
10. TiO2 Photocatalysis for the Redox Conversion of Aquatic Pollutants
Jaesang Lee, Jungwon Kim, and Wonyong Choi
11. Chlorine Based Oxidants for Water Purification and Disinfection
Gregory V. Korshin
12. Remediation of Chemically-Contaminated Waters Using Sulfate Radical Reactions: Kinetic Studies
Stephen P. Mezyk, Kimberly A. Rickman, Garrett McKay, Charlotte M. Hirsch, Xuexiang He, and Dionysios D. Dionysiou
13. Voltammetry of Sulfide Nanoparticles and the FeS(aq) Problem
G. R. Helz, I. Ciglenecki, D. Krznaric, and E. Bura-Nakic
14. Redox Reactivity of Organically Complexed Iron(II) Species with Aquatic Contaminants Timothy J. Strathmann
15. Fe2+ Sorption at the Fe Oxide-Water Interface: A Revised Conceptual Framework
Christopher A. Gorski and Michelle M. Scherer
16. Redox Driven Stable Isotope Fractionation
Jay R. Black, Jeffrey A. Crawford, Seth John, and Abby Kavner
17. Redox Properties of Structural Fe in Smectite Clay Minerals
Anke Neumann, Michael Sander, and Thomas B. Hofstetter
18. Reactivity of Zerovalent Metals in Aquatic Media: Effects of Organic Surface Coatings
Paul G. Tratnyek, Alexandra J. Salter-Blanc, James T. Nurmi, James E. Amonette, Juan Liu, Chongmin Wang, Alice Dohnalkova, and Donald R. Baer
19. Current Perspectives on the Mechanisms of Chlorohydrocarbon Degradation in Subsurface Environments: Insight from Kinetics, Product Formation, Probe Molecules, and Isotope Fractionation
Martin Elsner and Thomas B. Hofstetter
20. Degradation Routes of RDX in Various Redox Systems
Annamaria Halasz and Jalal Hawari
21. Role of Coupled Redox Transformations in the Mobilization and Sequestration of Arsenic
Janet G. Hering, Stephan J. Hug, Claire Farnsworth, and Peggy A. O>'Day
22. Redox Processes Affecting the Speciation of Technetium, Uranium, Neptunium, and Plutonium in Aquatic and Terrestrial Environments
Edward J. O'Loughlin, Maxim I. Boyanov, Dionysios A. Antonopoulos, and Kenneth M. Kemner
23. Rate Controlling Processes in the Transformation of Tetrachloroethylene and Carbon Tetrachloride under Iron Reducing and Sulfate Reducing Conditions
Elizabeth C. Butler, Yiran Dong, Lee R. Krumholz, Xiaoming Liang, Hongbo Shao, and Yao Tan
24. The Use of Chemical Probes for the Characterization of the Predominant Abiotic Reductants in Anaerobic Sediments
Huichun (Judy) Zhang, Dalizza Colón, John F. Kenneke, and Eric J. Weber
25. The Role of Transport in Aquatic Redox Chemistry
Wolfgang Kurtz and Stefan Peiffer
26. Evolution of Redox Processes in Groundwater
Peter B. McMahon, Francis H. Chapelle, and Paul M. Bradley
Editors' Biographies
Indexes
Author Index
Subject Index
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The specification in this catalogue, including without limitation price, format, extent, number of illustrations, and month of publication, was as accurate as possible at the time the catalogue was compiled. Occasionally, due to the nature of some contractual restrictions, we are unable to ship a specific product to a particular territory. Jacket images are provisional and liable to change before publication.
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